Publications

2019

(67) A. Zimpel, N. Danaf, B. Steinborn, M. Höhn, T. Bauer, W. Schrimpf, H. Engelke, E. Wagner, T. Bein, M. Barz, D. C. Lamb, U. Lächelt,* S. Wuttke,* Effect of different polymer coatings on MOF nanoparticles for better control of interactions at the biointerface, ACS Nano 2019, 13, 3884-3895. (DOI: 10.1021/acsnano.8b06287)

(66) [Hot Paper] B. Rühle, E. Virmani, H. Engelke, F. M. Hinterholzinger, T. von Zons, B. Brosent, T. Bein, A. Godt,* S. Wuttke,* A Chemiluminescent Metal-Organic Framework, Chem. Eur. J. 2019, 25, 6349-6354. (DOI: 10.1002/chem.201806041)

(65) B. M. Connolly, M. Aragones-Anglad, J. Gandara-Loe,c N. A. Danaf, D. C. Lamb, J. P. Mehta, D. Vulpe, S. Wuttke, J. Silvestre-Albero, P. Z. Moghadam, A. E. H. Wheatleya, D. Fairen-Jimenezb, Tuning porosity in macroscopic monolithic metal-organic frameworks for exceptional natural gas storage, Nat. Commun. 2019, accepted.

(64) W. Zhu, J. Guo, S. Amini, J. O. Agola, Y. Ju, A. Zimpel, J. Shang, A. Noureddine, F. Caruso, S. Wuttke, J. G. Croissant, C. J. Brinker, SupraCells: Living Mammalian Cells Coated within Functional Modular Nanoparticle-Based Exoskeletons, Adv. Mater. 2019, accepted. (DOI: 10.1002/adma.201900545)

(63) W. Zhu, J. Guo, J. O. Agola, J. G. Croissant, J. Shang, E. Coker, A. Zimpel, S. Wuttke, C. J. Brinker, Metal-Organic Framework Nanoparticle-Assisted Cryopreservation of Red Blood Cells, J. Am. Chem. Soc. 2019, accepted. (DOI: 10.1021/jacs.9b00992)
2018

(62) [Invited Perspective Article] S. Wuttke,* D. D. Medina, J. M. Rotter, S. Begum, T. Stassin, R. Ameloot, M. Oschatz, M. Tsotsalas,* Bringing porous organic and carbon-based materials towards thin film applications, Adv. Funct. Mater. 2018, 1801545. (DOI: 10.1002/adfm.201801545)

(61) [Invited Review] M. Peller,* K. Böll, A. Zimpel, S. Wuttke,* Metal-organic framework nanoparticles for magnetic resonance imaging, Inorg. Chem. Frontiers 2018, 5, 1760-1779. (DOI: 10.1002/adfm.201606314)

(60) T. Rhauderwiek, H. Zhaob, P. Hirschle, M. Döblinger, B. Buekend, H. Reinsch, D. de Vos,
S. Wuttke, U. Kolb, N. Stock, Highly stable and porous porphyrin-based zirconium and hafnium phosphonates – Electron crystallography as an important tool for structure elucidation, Chem. Sci. 2018, 9, 5467-5478. (DOI: 10.1039/C8SC01533C)

(59) [Front Cover and VIP paper] M. Modena, P. Hirschle, S. Wuttke,* T. Burg,* Mass Measurements Reveal Preferential Sorption of Mixed Solvent Components in Porous Nanoparticles, Small 2018, 14, 1800826. (DOI: 10.1002/smll.201800826)

(58) E. Virmani, J. M. Rotter, A. Mähringer, T. von Zons, A. Godt, T. Bein, S. Wuttke,* Dana D. Medina*, On-Surface Synthesis of Highly Oriented Thin Metal-Organic Framework Films through Vapor-Assisted Conversion, J. Am. Chem. Soc. 2018, 140, 4812-4819. (DOI: 10.1021/jacs.7b08174)

(57) W. Schrimpf, J. Jiang, Z. Ji, P. Hirschle, D. C. Lamb, O. M. Yaghi,* S. Wuttke,* Chemical Diversity in a Metal-Organic Framework, Nature Commun. 2018, 9:1647. (DOI: 10.1038/s41467-018-04050-w)

(56) [Invited Article] R. Freund, U. Lächelt, T. Gruber, B. Rühle, S. Wuttke,* Multifunctional efficiency: extension of the concept of atom economy to functional nanomaterials, ACS Nano 2018, 12, 2094-2105. (DOI: 10.1021/acsnano.8b00932)
2017

(46) [Invited Feature Article] M. Limont, L. Dreesen, S. Wuttke, Metal-organic framework nanoparticles in phodynamic therapy : Current status and perspectives, Adv. Funct. Mater. 2017, 27, 1606314. (DOI: 10.1002/adfm.201606314)

(50) [Invited Perspective Article] S. Wuttke, M. Lismont, A. Escudero, B. Rungtaweevoranit,
W. J. Parak, Positioning metal-organic framework nanoparticles within the context of drug delivery – A comparison with mesoporous silica nanoparticles and dendrimers, Biomaterials 2017, 123, 172-183. (DOI: 0.1016/j.biomaterials.2017.01.025)

(45) [Front cover] S. Wuttke, A. Zimpel, T. Bein, S. Braig, K. Ferkaljuk, A. Vollmar, D. Müller, K. H.- Talini, J. Schaeske, M. Stiesch, G. Wimann, P. Behrens, D. A. Bölükbas, S. Meiners, Validating metal-organic framework nanoparticles for their nanosafety in diverse biomedical applications, Adv. Health. Mater. 2017, 6. (DOI: 10.1002/adhm.201600818)

(49) R. Röder, T. Preiß, P. Hirschle, B. Steinborn, A. Zimpel, M. Höhn, J. O. Rädler, T. Bein, E. Wagner, S. Wuttke, U. Lächelt, Multifunctional Nanoparticles by Coordinative Self-Assembly of His-Tagged Units with Metal−Organic Frameworks, J. Chem. Am. Soc. 2017, 139, 2359-2368. (DOI: 10.1021/jacs.6b11934)

(51) [Invited] T. Preiß, A. Zimpel, S. Wuttke, J. O. Rädler, Kinetic Analysis of the Uptake and Release of Fluorescein by Metal-Organic Framework Nanoparticles, Materials 2017, 10, 216. (DOI: 10.3390/ma10020216)

(54) B. Illes, P. Hirschle, V. Cauda, S. Wuttke, H. Engelke, Exosome-coated Metal-Organic Framework Nanoparticles: An Efficient Drug Delivery Platform, Chem. Mater. 2017, 29, 8042-8046. (DOI : 10.1021/acs.chemmater.7b02358)

(52) M. Köppen, O. Beyer, S. Wuttke, U. Lüning, N. Stock, Synthesis, functionalisation and post-synthetic modification of bismuth metal-organic frameworks, Daltan Trans. 2017, 46, 8658-8663. (DOI : 10.1039/C7DT01744H)

(48) J. J. Mittag, B. Kneidl, T. Preiß, M. Hossann, S. Wuttke, H. C. Engelke, J. O. Rädler, Binding of blood plasma proteins to thermosensitive liposomes and its eﬀect on release studied by ﬂuorescence correlation spectroscopy, Eur. J. Pharm. Biopharm. 2017, 119, 215-223. (DOI : 10.1016/j.ejpb.2017.06.022)

(47) J. Lippke, B. Brosent, T. Zons, E. Virmani, S. Lilienthal, T. Preuße, M. Hülsmann, A. M. Schneider, S. Wuttke, P. Behrens, A. Godt, Expanding the group of porous interpenetrated
Zr-organic frameworks (PIZOFs) with linkers of different lengths, Inorg. Chem. 2017, 56, 748-761. (DOI: 10.1021/acs.inorgchem.6b01814)

(55) [Invited and with front cover] E. Virmani, O. Beyer, U. Lüning, U. Ruschewitz, S. Wuttke, Topology-guided functional multiplicity of iron(III)-based metal-organic frameworks, Mater. Chem. Frontiers 2017, 1, 1965-1974. (DOI : 10.1039/c7qm00263g)

(53) [Invited] B. Illes, S. Wuttke, H. Engelke, Liposome coated iron fumarate metal-organic framework nanoparticles for combination therapy, Nanomaterials 2017, 7, 351-362. (DOI :10.3390/nano7110351)

(44) T. Stassin, H. Reinsch, B. Van de Voorde, S. Wuttke, D. D. Medina, N. Stock, T. Bein, R. Ameloot, and D. De Vos, Adsorption and Reactive Desorption on Metal-Organic Frameworks : A Direct Strategy for Lactic Acid Recovery, ChemSusChem 2017,10, 643-650. (DOI: 10.1002/cssc.201601000)
2016

(43) A. Zimpel, T. Preiß, R. Röder, H. Engelke, M. Ingrisch, M. Peller, J. Rädler, E. Wagner, T. Bein, U. Lächelt, S. Wuttke, Imparting functionality to MOF nanoparticles by external surface selective covalent attachment of polymers, Chem. Mater. 2016, 28, 3318-3326. (DOI: 10.1021/acs.chemmater.6b00180)

(42) T. Rhauderwiek, S. Waitschat, S. Wuttke, H. Reinsch, T. Bein, N. Stock, Tunable Particle Size on two new Porphyrin-based MOFs with Gallium and Indium, Inorg. Chem. 2016, 55, 5312-5319. (DOI: 10.1021/acs.inorgchem.6b00221)

(41) [Invited] C. Hoch,* E. Siegfried,* S. Wuttke, Trendbericht zur Festkörperchemie, Na- chrichten aus der Chemie 2016, 64, 246 – 254. (DOI: 10.1002/nadc.20164047346)

(40) [Front Cover] W. Schrimpf, G. Ossato, P. Hirschle, S. Wuttke, D. C. Lamb,* Investigation of the co- dependence of morphology and fluorescence lifetime in a metal-organic framework, Small 2016, 27, 3651-3657. (DOI: 10.1002/smll.201600619)

(39) [Invited] P. Hirschle, T. Preiß, F. Auras, A. Pick, J. Völkner, D. Valdeperez, G. Witte, W. J. Parak, J. O. Rädler, S. Wuttke, Exploration of MOF nanoparticles sizes using various physical characterization methods – Is what you measure what you get?, CrystEngComm 2016, 18, 4359-4368. (DOI : 10.1039/C6CE00198J)

(38) M. S. Lohse, G. Naudin, S. Wuttke, D. Medina, T. Bein, Sequential Pore Wall Modification
in a Covalent Organic Framework, Chem. Mater. 2016, 28, 626–631.
(DOI : 10.1021/acs.chemmater.5b04388)
2015

(37) S. Wuttke, S. Braig, T. Preiß, A. Zimpel, J. Sicklinger, C. Bellomo, J. O. Rädler, A. M. Vollmar, T. Bein, MOF nanoparticles coated by lipid bilayers and their uptake by cancer cells, Chem. Commun. 2015, Advance Article. (DOI:10.1039/C5CC06767G)

(36) C. Dietl, H. Hintz, B. Rühle, J. S.Günne, H. Langhals, S. Wuttke, Switch-on fluorescence of a perylene dye functionalized metal-organic framework via postsynthetic modification, Chem. Eur. J. 2015, 21, 10714 – 10720.

[Backcover] Chem. Eur. J. 2015, 21, 10916-10916.

(35) E. Mühlbauer, A. Klinkebiel, O. Beyer, F. Auras, S. Wuttke, U. Lüning, T. Bein, Functionalized PCN‑6 metal‑organic frameworks, Microporous and Mesoporous Materials 2015, 216, 51 – 55. (DOI:10.1016/j.micromeso.2015.06.007)
2014

(34) H. Hintz, S. Wuttke, Solvent-Free and Time Efficient Postsynthetic Modification of AminoTagged
Metal−Organic Frameworks with Carboxylic Acid Derivatives, Chem. Mater. 2014, 26 (23), 6722–6728. (DOI: 10.1021/cm502920f)

(33) H. Hintz, S. Wuttke, Postsynthetic modification of an amino-tagged MOF using peptide coupling reagents: a comparative study, Chem. Commun. 2014, 78, 11472-11475. (DOI: 10.1039/C4CC02650K)

[Inside front cover] H. Hintz, S. Wuttke, Chem. Commun. 2014, 78, 11424-11424. (DOI: 10.1039/C4CC90357A)

(32) S. Wuttke, C. Dietel, F. M. Hinterholzinger, H. Hintz, H. Langhals, T. Bein, Turn-on fluorescence triggered by selective internal dye replacement in MOFs, Chem. Commun. 2014, 50, 3599-3601. (DOI: 10.1039/C3CC46591H)
2013

(31) F. M. Hinterholzinger, B. Rühle, S. Wuttke, K. Karaghiosoff, T. Bein, Highly sensitive and selective fluoride detection in water through fluorophore release from a metal-organic framework, Scientific Reports 2013, 2, 2562-2568. (DOI: 10.1038/srep02562)

(30) S. R. Miller, E. Alvarez, L. Fradcourt, T. Devic, S. Wuttke, P. S. Wheatley, N. Steunou, C. Bonhomme, C. Gervais, D. Laurencin, R. E. Morris, A. Vimont,M. Daturi, P. Horcajada and C. Serre, A rare example of a porous Ca-MOF for the controlled release of biologically active NO, Chem. Commun. 2013, 49, 7773-7775. (DOI: 10.1039/C3CC41987H).

(29) A. C. McKinlay, J. F. Eubank, S. Wuttke, B. Xiao, P. S. Wheatley, P. Bazin, J.-C. Lavalley, M. Daturi, A. Vimont, G. De Weireld, P. Horcajada, C. Serre, R. E. Morris, Nitric Oxide Adsorption and Delivery in Flexible MIL-88(Fe) Metal-Organic Frameworks, Chem. Mater. 2013, 25, 1592-1599. (DOI: 10.1021/cm304037x).
2012

(28) S. Wuttke, A. Negoi, N. Gheorghe, V. Kuncser, E. Kemnitz, V. Parvulescu, S.M. Coman, Sn-Doped hydroxylated MgF₂ catalysts for the fast and selective saccharification of cellulose to glucose, ChemSusChem 2012, 5, 1708-1711. (DOI: 10.1002/cssc.201200303)

(27) Y. Guo, S. Wuttke, A. Vimont, M. Daturi, J.-C. Lavalley, K. Teinz, E. Kemnitz, Synthesis and characterization of sol-gel prepared zinc fluoride, J. Mater 2012, 22, 14587-14593. (DOI: 10.1039/C2JM31357J)

(26) M. D.-Hardi, T. Devic, P. Horcajada, H. Chevreau, G. Maurin, G. Férey, D. Popov, C. Riekel, S. Wuttke, J.-C. Lavalley, A. Vimont, C. Serre, How interpenetration ensures rigidity and permanent porosity in a highly flexible hybrid solid, Chem. Mater. 2012, 24, 2486-2492. (DOI: 10.1021/cm300450x)

(25) [Invited] F. M. Hinterholzinger, S. Wuttke, P. Roy, T. Preuße, A. Schaate, P. Behrens, A. Godt, T. Bein, Highly oriented surface-growth and covalent dye labeling of mesoporous metal-organic frameworks, Dalton Trans. 2012, 41, 3899-3901. (DOI: 10.1039/C2DT12265K)

(24) S. Wuttke, P. Bazin, A. Vimont, C. Serre, J.-S. Chang, G. Férey, M. Daturi, Discovering the active sites in MIL-100(Fe) for C3 separation by using operando IR spectroscopy, Chem. – A Eur. J. 2012, 18, 11959-11967. (DOI: 10.1002/chem.201201006)

(23) A. Negoi, K. Teinz, E. Kemnitz, S. Wuttke, V. I. Parvulescu, S. M. Coman, Bifunctional nanoscopic catalysts for the one-pot synthesis of (±)-menthol from citral, Top. Cat. 2012, 55, 680-687. (DOI: 10.1007/s11244-012-9850-y)

(22) N. Candu, S. Wuttke, E. Kemnitz, S.M. Coman, V. I. Parvulescu, Replacing benzyl chloride with benzyl alcohol in heterogeneous catalytic benzylation of aromatic compounds, Pure and Appl. Chem. 2012, 84, 427-437. (DOI: 10.1351/PAC-CON-11-09-34)

(21) C. Dobrinescu, E.E. Iorgulescu, C. Mihailciuc, D. Macovei, S. Wuttke, E. Kemnitz, V.I. Parvulescu, S.M. Coman,One-pot hydroacetylation of menadione (vitamin K₃) to menadiol diacetate (vitamin K₄) by heterogeneous catalysis, Adv. Synth.&Catal. 2012, 354, 1301-1306. (DOI: 10.1002/adsc.201100718)
2011

(20) [Invited review] E. Kemnitz, St. Wuttke, S. Coman, Tailor made MgF₂-based catalysts via sol-gel synthesis, Eur. J. Inorg. Chem. 2011, 4773-4794. (DOI:  10.1002/ejic.201100539)

(19) P. Harcajada, F. Salles, S. Wuttke, T. Devic, D. Heurtaux, G. Maurin, A. Vimont, M. Daturi, O. David, E. Magnier, N. Stock, Y. Filinchuk, D. Popov, C. Riekel, G. Férey, C. Serre, How linker’s modification controls swelling properties of highly flexible iron(III) dicarboxylates MIL-88, J. Am. Chem. Soc. 2011, 133, 17839-17847. (DOI:  10.1021/ja206936e)

(18) [Insight Cover] Y.-K. Seo, J. W. Ji, J. S. Lee, Y. K. Hwang, C.-H. Jun, J.-S. Chang, S. Wuttke, A. Vimont, M. Daturi, S. Bourrelly, P. Llewellyn, P. Horcajada, C. Serre, G. Férey, Energy-Efficient Dehumidification over Hierachically Porous Metal-Organic Framworks as Advanced Water Adsorbents, Advanced Material 2012, 24, 806-810.
(DOI:  10.1002/adma.201104084)

(17) A. Fateeva, S. D.-Vinot, N. Heymans, T. Devic, J.-M. Greneche, S. Wuttke, S. Miller, A. Lago, C. Serre, G.D. Weireld, G. Maurin, A. Vimont, G. Férey, A series of porous 3-D coordination polymers based on iron(III) and porphyrin derivatives, Chem. Mater. 2011, 23, 4641-4651. (DOI:  10.1021/cm2025747)

(16) K. Teinz, S. Wuttke, B. Börno, J. Eicher, E. Kemnitz, Highly active and selective metal fluoride catalysts for the dehydrohalogenation of 3-Chloro-1,1,1,3-tetrafluorobutane, J. Cat. 2011, 282, 175-182. (DOI:  10.1016/j.jcat.2011.06.013)

(15) S.B. Troncea, S. Wuttke, E. Kemnitz, V.I. Parvulescu, S.M. Coman, Green synthesis of bioadditives to petrol fuel by catalytic acetylation of glycerol, Appl. Cat. B 2011, 107, 260-267. (DOI: 10.1016/j.apcatb.2011.07.021)

(14) [Invited] N. Candu, S. Wuttke, E. Kemnitz, S.M. Coman, V.I. Parvulescu, Friedel-Crafts alkylations on nanoscopic inorganic fluorides, Appl. Cat. A 2011, 391, 169-174. (DOI: 10.1016/j.apcata.2010.08.004)
2010

(13) A. Negoi, S. Wuttke, E. Kemnitz, D. Macovei, C.M. Teodorescu, V.I. Parvulescu, S.M. Coman, One-Pot Synthesis of Menthol Catalyzed by a Highly Diastereoselective Ionic Gold/MgF₂ Catalyst, Angew. Chem. Int. Ed. 2010, 49, 8134-8138. (DOI:  10.1002/anie.201002090)

(12) K. F. Gramham, K. T. Hindle, S. D. Jackson, D. J. M. Williams, S. Wuttke, Stereoselective Synthesis of Alicylic Amines, Top. Cat. 2010, 53, 1121-1125. (DOI:  10.1007/s11244-010-9544-2)

(11) [Insight Cover] J. W. Yoon, Y.-K. Seo,Y. K. Hwang,J.-S. Chang,H. Leclerc, S. Wuttke, P. Bazin, A. Vimont, M. Daturi,E. Bloch, P. L. Llewellyn, C. Serre, P. Horcajada, J.-M. Grenèche, A. E. Rodrigues, G. Férey; Controlled Reducibility of a Metal-Organic Framework with Coordinatively Unsaturated Sites for Preferential Gas Sorption, Angew. Chem. Int. Ed. 2010, 49, 5949-5952; Angew. Chem. 2010, 122, 6085-6088. (DOI: 10.1002/anie.201001230)

(10) S. Wuttke, A. Vimont, J. C. Lavalley, M. Daturi, E. Kemnitz; Infrared investigation of the acid and basic properties of a sol-gel prepared MgF₂, J. Phys. Chem. C 2010, 114, 5113-5120. (DOI: 10.1021/jp911584h)

(9) S. Wuttke, S.M. Coman, J. Kröhnert, F.C. Jentoft, E. Kemnitz; Sol-gel prepared nanoscopic metal fluorides – a new class of tunable acid-base catalysts, Catalysis Today 2010, 152, 2-10.  (DOI: 10.1016/j.cattod.2009.10.008)

(8) S. M. Coman, V.I.Parvulescu, S. Wuttke, E. Kemnitz; Synthesis of vitamin K₁ and K₁-chromanol by Friedel-Crafts alkylation in heterogeneous catalysis, ChemCatChem 2010, 2, 92-97. (DOI: 10.1002/cctc.200900205)
2009

(7) S. Wuttke, A. Lehmann, G. Scholz, M. Feist, A. Dimitrov, S. I. Troyanov, E. Kemnitz; Investigation of the fluorolysis of magnesium methoxide, Dalton Trans. 2009, 4729-4734. (DOI: 10.1039/B901030K)

(6) S.M. Coman, P. Patil, S. Wuttke and E. Kemnitz; Cyclisation of citronellal over heterogeneous inorganic fluorides – highly chemo – and diastereoselective catalysts to (±)-isopulegol, Chem. Commun. 2009, 460-462. (DOI: 10.1039/B817572A)
2008

(5) S. Wuttke, S. M. Coman,G. Scholz, H. Kirmse, A. Vimont,M. Daturi,S.L.M. Schroeder,E. Kemnitz; Novel Sol-Gel Synthesis of acidic MgF_2-x(OH)_xmaterials, Chem. Eur. J. 2008, 14, 11488-11499. (DOI: 10.1002/chem.200801702)

(4) S.M. Coman, S. Wuttke, A. Vimont, M. Daturi, E. Kemnitz; Catalytic performance of nanoscopic – AlF₃based catalysts in the synthesis of (all-rac)-a-tocopherol, Adv. Synth.&Catal. 2008, 350, 2517-2524. (DOI: 10.1002/adsc.200800411)

(3) M. N.-Amiry, G. Eltanany, S. Wuttke, St. Rüdiger, E. Kemnitz, J.M. Winfield; A comparative study of surface acidity in the amorphous, high surface area solids, aluminium fluoride, magnesium fluoride and magnesium fluoride containing iron(III) or aluminium(III), J. Fluorine Chem. 2008, 129, 366-375. (DOI: 10.1016/j.jfluchem.2008.01.017)

(2) A. Dimitrov, S. Wuttke, S. Troyanov and E. Kemnitz; Mg₆F₂(OMe)₁₀(MeOH)₁₄ – An Alkoxide Fluoride of an Alkaline Earth Metal, Angew. Chem. Int. Ed. 2008, 47, 190-192; Angew. Chem. 2008, 120, 196-198. (DOI: 10.1002/anie.200703516)
2007

(1) S. Wuttke, G. Scholz, St. Rüdiger and E. Kemnitz, Variation of sol–gel synthesis parameters and their consequence for the surface area and structure of magnesium fluoride, J. Mater. Chem. 2007, 17, 4980-4988. (DOI: 10.1039/B711855D)